Windows handles remapping to network different than remapping to a 2ed HDD and on a NT domain different than a home work group (the domain config could even have somthing to do with it) so it still could be the remap.
I could remap mine to my NAS to test but I don't have a domain setup ATM and I can't recreate your domain setup without having more info than would be safe for you to post in a public setting.
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